Wall compounds and methods of use

ABSTRACT

A wall compound for use in all applications and particularly well-suited for joining adjacent wallboards. The compound includes a latex resin, a thickener, fibers, and a filler material. In some embodiments, the repair compound is configured to exhibit at least one of yield stress and pseudoplastic-type behavior. In some embodiments, the compound includes hydrophobic and hydrophilic fibers of different morphologies. In some embodiments, the wall compound includes one or more associative thickeners.

CROSS REFERENCE TO RELATED APPLICATIONS

This application is a continuation of U.S. application Ser. No.16/641,210, filed Feb. 21, 2020, which is a national stage filing under35 U.S.C. 371 of PCT/US2018/047488, filed Aug. 22, 2018, which claimsthe benefit of U.S. Provisional Application No. 62/574,858, filed Oct.20, 2017, and U.S. Provisional Application 62/548,845, filed Aug. 22,2017, the disclosures of which are incorporated by reference in theirentireties herein.

TECHNICAL FIELD The present disclosure relates generally to materialssuch as paste or putties, which are used to join adjacent wall panelsand repair blemishes or defects in wall surfaces. BACKGROUND

In the construction of buildings and residential remodeling, one of themost common elements is gypsum wallboard, often known as drywall, usedin the construction of walls and/or ceilings. Walls made from gypsumwallboard are traditionally constructed by affixing panels to wood studsor metal framing. Two side-by-side panels disposed in the same planewill form a joint seam between them on vertical walls and horizontalceilings. The joints between adjacent wallboard panels are filled usinga composition commonly called joint compound to conceal the joints andcreate the appearance of a monolithic surface. The side edges of thedrywall panels can be tapered, allowing the joint compound to be appliedto the seam, between adjoining panels, in such a way that a monolithicsurface is created when finished.

When cavities, recesses, holes, etc., are present (due to imperfectionsor damage) in exterior or interior surfaces such as walls and ceilings,it is common to use a wall repair compound, and in particular aspackling compound, to fill such cavities. Conventional spacklingcompounds often include one or more inorganic fillers, one or morepolymeric resin binders, and various thickeners and other additives.Lightweight spackling compounds have been developed that often contain,among other inorganic fillers, relatively low density fillers such asglass bubbles, hollow silica, or expanded perlite. After the spacklingcompound is applied to a wall, the water evaporates over time resultingin the formation of a dried, hardened material that can be sanded,painted, etc. While spackling compounds and joint compounds do many ofthe same things and are both smeared onto walls to hide flaws, spacklingcompounds are generally lighter, dry more quickly, sand more easily, andare more expensive than joint compounds. For simplicity, the term “wallcompound” as used throughout the present disclosure is inclusive ofspackling compounds and joint compounds.

The procedure for concealing the joint between adjacent wallboards, andthereby producing a smooth seamless wall surface, typically includesapplying soft wet joint compound within the joint or seam 3 formed bythe abutting edges of adjacent wallboard panels 1, 2 using a trowel 4 orthe like. One typical implementation of this process is depicted inFIG. 1. A fiberglass, cloth, or paper reinforcing tape material (e.g.,joint reinforcing tape) 10 is embedded within the wet joint compound 20,and the compound 20 is allowed to harden. After the joint compound 20has hardened, at least a second layer of joint compound 30 is appliedover the joint 3 and tape 10 to completely fill the joint 3 and providea smooth surface. This layer is also allowed to harden. One or moreadditional compounds 40, either joint compounds or finishing compounds,may also be applied and allowed to harden. Upon hardening of the finalcoat layer, the joint seam 3 is sanded smooth to eliminate surfaceirregularities. Paint or a wall covering, such as wall paper, can thenbe applied over the joint compound so that the joint and the drywallcompound may be imperceptible under the paint or wall covering. The samejoint compound can also be used to conceal defects caused by the nailsor screws used to affix the wallboard panels to the studs or otherframing, or to repair other imperfections in the wallboard panels.

The taping operation referenced above involves several repetitive steps,making it a time-consuming process in drywall finishing. One tapingprocess requires a mechanical tool commonly referred to as a bazooka,which is fitted with a roll of paper tape and filled with ready mixedjoint compound which has been mixed with sufficient water. As the headof the bazooka is placed over the joint and moved down the wall, thetape advances and the backside is coated with a thin coat of jointcompound which holds it loosely to the wallboard. A second worker willoften have to follow behind the bazooka wiping the tape tight to thewall and removing excess joint compound from over the tape. If the jointcompound does not flow evenly over the back side of the tape, blistersmay occur which are often not seen until the taping coat is dry. In thiscase, the tape must be removed from the joint and a thin film of jointcompound and piece of tape reapplied before the next stage of finishingcan be reached.

The materials conventionally used to finish wall assemblies createsignificant inefficiencies in the process and also require an advancedlevel of skill to use effectively. For example, existing joint compoundscan require up to three separate coats to be applied to fasteners aswell as multiple coats applied to flat seams between boards in the sameplane and to corner seams. Each coat must separately dry whichintroduces significant downtime in the construction process,particularly since the other construction trades ordinarily cannot workas effectively, if at all, inside the building while the wall finishingoccurs. Each layer of joint compound can require about a day to dry, andit can typically take several days to weeks to install the gypsum boardand finish the flat joints, fasteners, and corner trims for a typicalnew construction of a home. Since all joint filling operations arehighly labor intensive, the total cost is often extremely high whencompared to the cost of the composition employed.

SUMMARY

The inventors of the present disclosure recognized that the process forjoint filling could be significantly improved by reducing the number ofapplications of joint compound and eliminating the taping step. In lightof the above, the inventors of the present disclosure recognized a needfor a tape free joint compound that provides a quick dry with minimal tono shrinking and/or cracking once dried. Furthermore, an improved jointcomposition useable without tape would desirably be easily spread over agiven joint area, without at least one of sagging or running onceapplied.

The present inventors discovered that prior compositions purporting tooffer the above properties often failed to provide at least one ofcompositional stability, ease of application, workable open time,relatively short drying times, and resistance to sagging. Attempts toalleviate issues with sagging in such compositions often deleteriouslyimpacted the ease of application and/or severely prolonged the dryingtime. Similarly, attempts to improve the ease of application resulted incompositions that were not storage-stable, and/or compositions thatsagged upon most geometries of application. Exploration of impact on thedesired performance by use of traditional rheology modifiers, such ascellulosic rheological modifiers and gelling clays, as well as dustreducing additives (e.g., oils, waxes, glycols, and other petroleumderivatives) yielded compounds that lacked componentsolubility/stability or adhered poorly to requisite wallboard surfaces.

Surprisingly, the present inventors discovered that select packages ofassociative thickeners can be combined with low shrinkage fillers in alatex resin to provide a wall compound meeting or exceeding theperformance requirements expected and desired of joint compounds. Thepresent disclosure accordingly provides wall compounds that have reducedto rapid dry times while still possessing desirable attributes of easyapplication, workable open time, and resistance to sagging. The wallcompounds further provide low to no shrinkage and low to no crackingupon drying. Satisfactory filling can be effected in two applications,and often in a single application, dramatically reducing labor cost andincreasing efficiency in interior building construction.

Some aspects of the present disclosure are directed toward a wallcompound particularly well-suited for joint seam filling. In someembodiments, the compound can be used to fill a joint seam in theabsence of a reinforcement tape. Wall compounds of the presentdisclosure can also be suitable for filling and repairing relativelylarge holes or cavities (e.g., major dimension of at least 2 inches),cracks or other imperfections in a surface (such as, for example, agypsum wallboard surface), as well as virtually any other, smaller wallsurface imperfection. The wall compound includes a latex resin, athickener package, fibers, and a filler material. The wall compound isconfigured to exhibit at least one of yield stress andpseudoplastic-type behavior. In some embodiments, wall compounds of thepresent disclosure include one or more of (1) hydrophobic andhydrophilic fibers of different morphologies, (2) associative,polyurethane containing thickeners, (3) a bimodal distribution of hollowglass microspheres from two different strength/size curves, and (4)organometallic adhesion promoters.

Further embodiments provide a method for affixing and holding two panelstogether at a joint seam, comprising a step of creating a joint seam bypositioning two panels side-by-side such that the panels abut; and astep of applying the wall compound to the joint seam and some panelsurface area around the seam. At least some embodiments, the method isperformed without joint reinforcement tape. In other embodiments, thewall compound is provided as part of a kit. In some embodiments, the kitincludes a tool.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is an illustration of the procedure for concealing the jointbetween adjacent wallboards; and

FIG. 2 is a graph illustrating the flow of wall compounds underescalating shear stress.

DETAILED DESCRIPTION

Various embodiments and implementations will be described in detail.These embodiments should not be construed as limiting the scope of thepresent disclosure in any manner, and changes and modifications may bemade without departing from the spirit and scope of the inventions. Forexample, many of the embodiments, implementations, and examples arediscussed with specific reference to wall repair, but these should notbe construed to limit the application scope to this one exemplaryimplementation. Further, only some end uses have been discussed herein,but end uses not specifically described herein are included within thescope of the present disclosure. As such, the scope of the presentdisclosure should be determined by the claims.

Wall compounds of the present disclosure are suitable for filling ajoint seam, with or without reinforcement tape. In particularlyadvantageous embodiments, the wall compounds can fill a seam and providea monolithic surface without the need for joint reinforcement tape. Thewall compounds of the present disclosure exhibit a yield stress and/orpseudoplastic-type behavior and can be lightweight (e.g., having adensity of not more than 6 lbs/gal, alternatively not more than 5lbs/gal, alternatively not more than 4 lbs/gal, and alternatively notmore than 3.5 lbs/gal).

The wall compounds of the present disclosure possess, in one or morecombinations, three identifiable rheological properties: a low viscosityunder large stress to make application easy, a high viscosity under lowstress to prevent creeping flow after application, and yield stressbehavior to resist sagging or running after application.

Wall compounds of the present disclosure generally include a latexresin, a thickener package, fibers, and a synthetic filler material.Other optional ingredients may be included in various other embodiments.In some embodiments, the thickener in combination with the fibersproduces a wall compound exhibiting yield stress fluid and/orpseudoplastic-type behavior. In some embodiments, the filler materialhas a bimodal distribution of glass bubbles, which results in alightweight wall compound. In other embodiments, the filler material isa single class of substantially spherical synthetic filler. In someembodiments, the wall compound is a wall repair compound. In someembodiments, the wall compound is a wood repair compound.

Resin

The wall compounds of the present disclosure comprise at least one latexresin or resin binder, such as a polymeric resin binder conventionallyviewed as being useful with wall compounds. Such binders are oftensupplied as an aqueous latex emulsion (for example, comprising between15-60 percent solids of polymeric resin binder, in water). Exemplarypolymeric resins potentially suitable for binders of the presentdisclosure include, for example, the well-known vinyl acrylic polymersand copolymers, acrylic polymers and copolymers, polyvinyl acetatepolymers and copolymers, ethylene vinyl acetate polymers and copolymers,styrene-butadiene polymers and copolymers, polyacrylamide polymers andcopolymers, natural rubber latex, natural and synthetic starch, casein,and the like. Such binders can be used alone or in combination with oneanother. In some embodiments, the resin or resin binder is 100%acrylate. In some embodiments, the resin or resin binder portion of thewall compound includes at least one latex resin and at least onenon-latex resin. In some embodiments, the latex and non-latex resin forma uniform blend.

In some embodiments, the latex resin is an acrylic latex emulsionbinder. For example, the resin can be a vinyl acrylic latex emulsionbinder available from Arkema Coating Resins of Cary, N.C., under thetrade designation ENCOR 379G. The ENCOR 379G latex is a high molecularweight polymer that delivers very high scrub resistance and durabilityin both interior and exterior architectural coatings. This polymercombines high molecular weight with an optimized glass transitiontemperature to produce flexible films with excellent grain crackresistance and long-term durability. Further, vinyl acrylic latexemulsions, such as the ENCOR 379G, can exhibit sufficient tolerance toloading of the optional filler material described below.

In some embodiments, the acrylic latex emulsion binder (e.g., ENCOR379G) is combined with another latex binder (e.g., DOW ENCOR 627 or 626or 631 or NEOCAR Latex 2300 or NEOCAR Latex 2535).

The latex emulsion resin can comprise at least about 20, 30, 40, or 50percent, by weight, of the wall compound in some embodiments.

In some embodiments, the resin or resin binder has a Tg of greater than10 degrees C. In some embodiments, the resin or resin binder has a Tg ofgreater than 20 degrees C. In some embodiments, the resin or resinbinder has a Tg of greater than 25 degrees C. In some embodiments, theresin or resin binder has a Tg of greater than 29 degrees C.

Thickener

The wall compounds of the present disclosure include a thickenerpackage. The thickener package provides an enhanced initial viscosity(i.e., viscosity under low or no shear stress) for the wall compoundssuch that the compound does not excessively sag, slump, or run (e.g.,when applied to a vertical wall) but yields to flow easily oncesufficient shear stress is applied.

Suitable thickeners are compatible with the composition, meaning thatwhen the thickener is combined with the resin binder, a smooth-flowing,homogeneous liquid mixture is formed, from which, a dried coating isobtained at room temperature. Addition of the thickener typically shouldnot coagulate the composition (e.g., form semi-solid or solid clumpsand/or gel particles). Preferably, the thickener imparts pseudoplastic(shear thinning) behavior to the composition, meaning that the viscositydecreases with increasing shear rate. In some embodiments, the thickenerimparts “short viscosity” to the composition, meaning that a filament ofthe composition breaks at very short lengths and the composition doesnot form “strings” when drawn out. The amount of thickener required inthe composition depends on the thickener chemistry and viscositydesired.

The thickeners may include polyvinyl alcohol (PVA), clay materials, acidderivatives, acid copolymers, urethane associate thickeners (VAT),polyether urea polyurethanes (PEUPU), polyether polyurethanes (PEPU), ormixtures thereof. Other examples of suitable thickeners include alkaliswellable emulsions (ASE) such as sodium or ammonium neutralized acrylicacid polymers; hydrophobically modified alkali swellable emulsions(HASE) such as hydrophobically modified acrylic acid copolymers; andstyrene-maleic anhydride terpolymers (SMAT); associative thickeners suchas hydrophobically modified ethoxylated urethanes (HEUR);hydrophobically modified polyethers (“HMPE”); and cellulosic thickenerssuch as methyl cellulose ethers, hydroxymethyl cellulose (HMC),hydroxyethyl cellulose (HEC), hydrophobically-modified hydroxy ethylcellulose (HMHEC), sodium carboxymethyl cellulose (SCMC), sodiumcarboxymethyl 2-hydroxyethyl cellulose, 2-hydroxypropyl methylcellulose, 2-hydroxyethyl methyl cellulose, 2-hydroxybutyl methylcellulose, 2-hydroxyethyl ethyl cellulose, and 2-hydoxypropyl cellulose.Associative thickening may involve dynamic, non-specific interactions ofhydrophobic end groups of a thickener molecule with itself and withother components of a formulation. Associative thickening isparticularly suitable to water-based wall compounds of the presentdisclosure, where the thickener is able to modify gloss, flow, shear,leveling, spatter resistance, or other properties.

The wall compounds of the present disclosure comprise a thickenerpackage including at least one polyurethane-containing thickener as aprimary thickener and an associate thickener as a secondary thickener.In certain implementations, the thickener packaged includes HEUR and analkali swellable emulsion. HEUR can be assembled from a hydrophilic diol(e.g., a polyethylene glycol of 6,000-8,000 g/mol), a polyisocyanate,and a hydrophobic monol or diol. The cycloaliphatic polyester polyolscan be utilized to supplement or replace the hydrophobic monol or diol.In some embodiments, the thickener package includes HEUR and an ASE. Inother embodiments, the thickener packaged includes HEUR and HASE. In yetother embodiments, the thickener package includes HEUR, HASE, and ASE.In yet further embodiments, the thickener package includes an HASE.Exemplary HEUR and HASE associative thickeners and their methods ofpreparation may be found in, e.g., U.S. Pat. No. 8,871,817 (Turk etal.); U.S. Pat. No. 8,697,797 (Suau et al.); U.S. Pat. No. 8,524,649(Leyrer et al.); U.S. Pat. No. 8,461,213 (Muezenberg et al.); U.S. Pat.No. 8,334,357 (Schieferstein et al.); U.S. Pat. No. 5,281,654 (Eisenhartet al.); and 4,155,892 (Emmons et al.). Exemplary, commerciallyavailable HEUR thickeners are sold under the trade designation ACRYSOL®RM-12W by Dow Chemical, Midland, Mich., USA and COAPUR XS 83, by Coatex,Inc., Genay, France. An exemplary, commercially available ASE is soldunder the trade designation ACRYSOL® 6038A by Dow Chemical. ExemplaryHASE thickeners are available from Coatex, Inc. under the tradedesignations THIXOL 53L, RHEOTECH 4800, and RHEOTECH MO2.

The thickener package can be included in any suitable amount, e.g., toachieve a desired viscosity. In some embodiments, the thickener packageis included in an amount from about 0.01% to about 5%, by weight of thewet composition, such as from about 0.01% to about 3%, from about 0.01%to about 2%, from about 0.1% to about 2%, or from about 0.1% to about1%, by weigh of the total wall compound as formulated.

The wall compound typically comprises from about 0.001 wt. % to about 1wt. %, about 0.01 wt. % to about 0.6 wt. % and 0.05 wt. % to 0.25 wt. %of the primary, polyurethane based thickener, by weight of the totalwall compound as formulated.

Below this range, the thickener may not provide sufficient increase inviscosity, and the composition may be too runny or insufficiently stablefor wallboard joining applications. Above this range the compositiondoes not spread as easily or does not exhibit the desired yield stressbehavior.

Alternatively, other thickeners conventionally employed with wallcompounds may be used, for example to provide an increased viscosity ofthe wall compounds such that the compound does not excessively sag,slump or run (e.g., when applied to a vertical wall).

While various ones of thickeners described above may be used with thewall compounds of the present disclosure, it has been found thatclay-type thickeners are too dense for use in the wall compoundsdescribed herein. Further, it has been found that cellulosic thickenersmay impart excessive lubricity to the wall compound (as formulated withthe other components or ingredients of the present disclosure) and makeit hard for the wall compounds described herein to stick in the seam orhole. Accordingly, in presently preferred implementations, the thickenerpackage does not include either one of clay-type thickeners andcellulosic thickeners.

Fibers

The wall compounds of the present disclosure further include fibers. Insome embodiments, the wall compounds include two (or more) differenttypes of fibers. In some embodiments, the fibers are selected inconjunction with the selected thickener to impart yield stress behaviorand/or pseudoplastic behavior into the wall compound, as well as toenhance performance of the wall compound in joining adjacent wallboardsor repair defects in a wall surface.

The fibers can assume a variety of forms, and in some embodiments,include a first fiber type selected to provide one or more desiredperformance attributes, and a second fiber type that is also selected toprovide desired performance attributes, but that differ from that orthose of the first fiber type. For example, the first fiber type can beselected to provide one or more of general reinforcement, crackresistance, reduced shrinkage, viscosity control, particle suspension,shear thinning, improved dimensional stability without absorbing otheringredients or reducing shelf life, etc. The second fiber type can beselected to provide porosity control and absorbency (as well asreinforcement).

With the above explanations in mind, in some embodiments, the firstfiber type is a hydrophobic fiber and the second fiber type is ahydrophilic fiber. In related embodiments, a nominal length of the firstfiber type is less than the nominal length of the second fiber type, forexample on the order of 10× less.

In some embodiments, the fibers of the present disclosure include amixture of hydrophobic dry fibrillated polyethylene fibers andhydrophilic rayon fibers. The dry fibrillated polyethylene fibers canhave a nominal size that is less than a nominal size of the hydrophilicrayon fibers. For example, the hydrophobic dry fibrillated polyethylenefiber can have nominal dimension on the order of 15 microns in diameterand 0.55-0.80 mm in length, whereas the hydrophilic rayon fibers canhave nominal dimensions on the order of 4.5 denier by 0.5 inch. The dryfibrillated polyethylene fibers as combined with the thickener provideone or more of general reinforcement, crack resistance, reducedshrinkage, viscosity control, particle suspension, shear thinning, andimproved dimensional stability without absorbing other ingredients orreducing shelf life. The hydrophilic rayon fibers as combined with thethickener provide one or more of porosity control and absorbency, andreinforcement.

In some embodiments, the two different fiber types augment desiredperformance attributes of the thickeners described above, allowing forthe use of a lesser amount of the thickener (as compared to conventionalspackling compound formulations). The hydrophilic rayon fiber (forexample) can serve to distribute stress over a larger area in the wallcompound upon drying. Regardless, in some embodiments, the thickener andfibers combine to render the wall compound to exhibit apseudoplastic-type behavior as described below.

In some embodiments, the wall compound of the present disclosure mayinclude less than about 1 percent by weight of the hydrophobic dryfibrillated polyethylene fibers (or equivalent fibers), and furtherinclude less than about 1 percent by weight of the hydrophilic rayonfibers (or equivalent fibers). In related embodiments, the wall compoundof the present disclosure may include a greater amount (by weight) ofthe hydrophilic rayon fiber (or equivalent fibers) than the hydrophobicdry fibrillated polyethylene fibers (or equivalent fibers).

In some embodiments, the fiber(s) is/are present in total in an amountof no greater than about 3 percent, no greater than about 2 percent, orno greater than about 1 percent, by weight of the total wall compound asformulated.

Filler

The wall compounds of the present disclosure further include a filler.In some embodiments, the filler is an inorganic filler system thatcomprises one or more inorganic fillers. In some embodiments, theinorganic filler system includes synthetic inorganic fillers. The term“synthetic inorganic filler” as used herein includes any filler that hasbeen transformed, regenerated, recrystallized, reconstituted, etc., froman original state which may be its naturally occurring, mined state intoits current state by a chemical synthesis process (e.g., precipitatedfrom solution, generated by flame hydrolysis, etc.) or by a physicalsynthesis process (e.g., precipitated from a gaseous phase, solidifiedby way of a sol-gel process, etc.). The term “synthetic inorganicfiller” as used herein also includes any filler that has beensubstantially transformed from an original state (which may be itsnaturally occurring, mined state) into its current state by a physicalsynthesis process of being brought into an at least partially softenedor molten state and then solidified by cooling, such that anysubstantially crystalline structure that may have existed in the naturalstate is substantially erased such that the material is now in asubstantially amorphous form (e.g., comprising less than about 0.5percent crystallinity by weight). Such processes may include, forexample, melt processing, flame-fusion and the like.

Using the definitions provided above, synthetic inorganic fillersinclude, for example, so-called glass bubbles or microspheres (such asthose available from 3M Company of St. Paul, Minn., under the tradedesignation 3M Glass Bubbles), ceramic microspheres (such as thoseavailable from 3M Company under the trade designation 3M CeramicMicrospheres), synthetic clays (e.g., synthetic silicate clays such asthose available under the trade designation Laponite from Southern ClayProducts of Gonzales, Tex.), precipitated silica, fumed silica, vitreoussilica, synthetic titanium dioxide (as made, for example, by the sulfateprocess or the chloride process), synthetic (precipitated) calciumcarbonate (as made, for example, by passing carbon dioxide through asolution of calcium hydroxide), and the like. In this context, the term“synthetic inorganic fillers” includes such synthetic inorganic fillersas have been modified to include organic surface groups, coatings, etc.

In certain embodiments, the synthetic inorganic fillers used hereincomprise a bimodal particle size mixture of larger synthetic inorganicfiller particles and smaller synthetic inorganic filler particles. Invarious embodiments, the synthetic inorganic filler used hereincomprises a bimodal particle size mixture of synthetic inorganic fillerparticles comprising a particle size ratio of larger size filler tosmaller size filler (as obtained by rationing the medium particle sizeof the two filler populations) of at least about 5:1. Other embodimentsof the present disclosure lack a bimodal distribution and feature oneaverage size of filler particles.

In some embodiments, such synthetic inorganic fillers are comprised ofsubstantially spherical particles. In this context, the term“substantially spherical” denotes that a substantial majority of theparticles are spherical except for such occasional deviations,deformities, etc., as are known to those of skill in the art to beoccasionally encountered in the manufacturing processes used to producethe particles (for example, somewhat misshapen particles mayoccasionally be produced, two or more particles may agglomerate oradhere to each other, and so on).

Suitable substantially spherical synthetic inorganic fillers as definedherein include so-called glass bubble and ceramic microspheres. Suchglass bubbles can be synthesized, for example, by a process as describedin U.S. Pat. Nos. 3,365,315 and 4,391,646, incorporated herein in theirentirety. Such ceramic microspheres can be synthesized, for example, bysol-gel processes, as described for example in U.S. Pat. Nos. 3,709,706and 4,166,147, incorporated herein in their entirety. Other methodspotentially useful for making ceramic particles and/or microspheres aredescribed in, for example, U.S. Pat. No. 6,027,799, incorporated hereinin its entirety.

In some embodiments, the synthetic inorganic filler used hereincomprises a bimodal particle size mixture of larger substantiallyspherical synthetic inorganic filler particles and smaller substantiallyspherical synthetic inorganic filler particles. In related embodiments,the synthetic inorganic filler used herein comprises a bimodaldistribution or mixture of first and second substantially sphericalsynthetic inorganic filler particles, with a density and/or strength ofeach of the first substantially spherical synthetic inorganic fillerparticles being greater than a density of each of the secondsubstantially spherical synthetic inorganic filler particles. In furtherrelated embodiments, the synthetic inorganic filler comprises a bimodaldistribution of hollow glass microspheres from two differentstrength/size curves. For example, the first substantially sphericalsynthetic inorganic filler particles are glass bubbles or microsphereshaving a mean particle size on the order of 50-55 microns and a densityon the order of 0.2 g/cc, and the second substantially sphericalsynthetic inorganic filler particles have a mean particle size on theorder of 20 microns and a density on the order of 0.45 g/cc. Forexample, the first substantially spherical synthetic inorganic fillerparticle can be Glass Bubbles available from 3M Company of St. Paul,Minn. under the trade designation K20, and the second substantiallyspherical synthetic inorganic filler particles can be Glass Bubblesavailable from 3M Company of St. Paul, Minn. under the trade designationiM16K.

The K20 glass bubble and the iM16K glass bubble exhibit different sizeand strength properties. When collectively employed as part of a wallcompound, it has surprisingly been found that the synthetic inorganicfiller (as a bimodal distribution) provides sufficient strength for theresultant wall compound while reducing the wall compound's density (ascompared to conventional spackling compounds). In some embodiments, thesynthetic inorganic filler comprises a bimodal mixture of larger, lessdense glass bubbles (e.g., K20 Glass Bubbles) at about 20-30 percent byweight, and about 2-10 percent by weight of the second, smaller/harderglass bubble (e.g., iM16K Glass Bubbles).

Optional Ingredients

Wall compounds of the present disclosure may optionally include one ormore additional components for various purposes. Exemplary additivesinclude, but are not limited to, adhesion promoters, activators,smoothing agents, solvents, dispersing agents, surfactants, humectants,colorants, and preservatives.

For example, an adhesion promoter can be employed to provide secureattachment of the wall compound to a wall and/or ceiling surface. Theadhesion promoter can assume a variety of forms as known to those ofskill in the art, and can include a titanium alkoxide adhesion promoter,such as an adhesion promoter available from Chartwell International,Inc. under the trade designation B-515.71W. In some embodiments, thewall compounds may include less than about 1 percent by weight of anadhesion promoter.

In some embodiments, the wall compounds of the present disclosure caninclude an activator or pH control agent to activate one or more of thethickeners described above (e.g., an HASE thickener may not activate orthicken the mixture at a pH less than 8.5). For example, and asdescribed in greater detail below, in some embodiments, formulation ofthe wall compound can include adjustment of the pH to about 9 to allowfor activation of the thickener. Where provided, the activator or pHcontrol agent can assume a variety of forms known in the art andappropriate for use with a wall compound, and for example can be anamino alcohol such as available from Dow Chemical Company under thetrade designation AMP-95. Where provided, the wall compound can includeless than about 0.15 percent by weight of the activator or pH controlagent.

In some embodiments, the wall compounds of the present disclosure mayinclude one or more smoothing agents, such as one or more organic ethersmoothing agents, found to advantageously affect the consistency of thecompound. In some embodiments, the optional smoothing agent, such as anorganic ether smoothing agent, at the concentrations disclosed hereincan impart a smooth consistency to the wall compound (absent thesmoothing agent, the wall compound may take on a crumblier appearance)such that the wall compound is more easily spreadable it does not run,sag, slump or crumble, once applied, e.g., to a vertical wall. Incontrast to the above-described thickeners, such optional smoothingagents appear to function to reduce the apparent viscosity of the wallcompound rather than to increase it (while, again, not causingunacceptable sagging or slumping). Some examples of acceptable smoothingagents useful with the wall compounds of the present disclosure aredescribed in U.S. Pat. No. 8,507,587, the teachings of which areincorporated herein in their entirety.

In various embodiments, the wall compounds described herein may includeone or more organic ether smoothing agents. In some embodiments, theorganic ether smoothing agent(s) is/are present in total in an amount ofat most about 2.5 percent, at most about 1.5 percent, or at most about0.5 percent, by weight of the total wall compound as formulated. Invarious additional embodiments, the one or more organic ether smoothingagents are present in total in an amount of at least about 0.025percent, at least about 0.05 percent, or at least about 0.15 percent, byweight.

Suitable organic ether smoothing agents may be chosen, for example, fromthose products available from Dow Chemical under the trade designationsDOW P-Series Glycol Ethers and DOW E-Series Glycol Ethers (including,for example, various products available under the trade designationsDOWANOL, CARBITOL, and CELLOSOLVE), and mixtures thereof. In someembodiments, organic ether smoothing agents are chosen from organicethers that comprise exactly one hydroxyl group and exactly one ethergroup. This group includes, for example, propylene glycol butyl ether(available from Dow Chemical under the trade designation DOWANOL PnB),propylene glycol methyl ether (available from Dow Chemical under thetrade designation DOWANOL PM), as well as other products available fromDow Chemical under the DOWANOL, CARBITOL, and CELLOSOLVE tradedesignations, and mixtures thereof. In other embodiments, optionalsmoothing agents are chosen from organic ethers that comprise exactlyone hydroxyl group and exactly two ether groups. In yet otherembodiments, optional smoothing agents are chosen from organic ethersthat comprise exactly one hydroxyl group and exactly three ether groups.In yet other embodiments, optional smoothing agents are chosen fromorganic ethers that comprise at least one ether group and that do notcontain any hydroxyl groups.

In addition to the components discussed above, other components may beadded to the wall compound. These may include, for example, water, whichmay be added at the end of the production process, for final adjustmentof e.g., viscosity. Thus, in certain embodiments, water (in addition tothe water optionally present in the aqueous acrylic latex binderemulsion) may be added to the formulation.

The components may be stabilized in a bulk water phase by employing oneor more surfactants. In various embodiments, the surfactant is anionicin nature and is the structure thereof not otherwise particularlylimited. Non-limiting examples of anionic surfactants include ammonium,sodium, lithium, or potassium salts of lauryl sulfonic acid, dioctylsodium sulfosuccinic acid, ammonium, sodium, lithium, or potassium saltsof perfluorobutanesulfonic acid, ammonium, sodium, lithium, or potassiumsalts of perfluorooctanesulfonic acid, ammonium, sodium, lithium, orpotassium salts of perfluorooctanoic acid, sodium dodecyl sulfate,sodium dodecylbenzenesulfonate, sodium laureth sulfate, sodium lauroylsarcosinate, sodium myreth sulfate, sodium pareth sulfate, ammonium,sodium, lithium, or potassium salts of stearic acid, and combinations ofone or more thereof. A dispersing agent may be added to the wallcompound composition for wetting and/or stabilization purposes. Thedispersing agent can be a non-ionic or an anionic compound, typically apolymer, such polyvinyl pyrrolidone. Such dispersing agents are known inthe art. The proportion of dispersing agent and/or surfactant willtypically depend upon the dispersant or surfactant or combinations usedand the particular wall compound composition.

The wall compounds described herein may further include humectants tocontrol loss of water or other solvent during use or storage. Suitablehumectants for use in the compositions include polyfunctional alcohols,such as propylene glycol, glycerol, polyglycerols, trimethylol propane,polyether glycols, sorbitol and/or low molecular weight starchhydrolyzates which have been converted into the corresponding polyols byreduction with hydrogen, and mixtures thereof.

Other additives that may be present include preservatives that may haveadvantageous effects on the wall compound during storage and may alsoserve to minimize the degree to which mold or fungus may grow on thedried wall compound. Thus, in certain embodiments, the wall compoundsdisclosed herein can optionally comprise at least about 0.1, 0.2 or 0.3percent by weight of a preservative or preservatives. In furtherembodiments, the wall compounds disclosed herein optionally comprise atmost about 0.8, 0.6 or 0.4 percent by weight of a preservative orpreservatives. Suitable preservatives include, for example, thoseavailable under the designation Mergal 186 and Polyphase P2OT, from TroyCorporation of Florham Park, N.J. The wall compounds disclosed hereincan also comprise dust reducing additives, which in some circumstancesmay serve to further reduce the quantity of airborne dust particlesgenerated when sanding the dried, hardened wall repair compound.Exemplary additives may include oils (such as mineral oils, vegetableoils, and animal oils), waxes (including natural and synthetic waxes),and the like.

To enhance the ability of the wall compound to “hide” or blend in withthe visual appearance of the wall or ceiling surface, the wall compoundmay also optionally include one or more colorants or primers. Onesuitable colorant or primer is, for example, titanium dioxide. While notwishing to be bound by theory, it is believed that titanium dioxidereflects light and thereby effectively hides differences in thesubstrate color/appearance when added to the wall compound formulation.Another exemplary suitable colorant is carbon black. Specificcommercially available colorants suitable for use in the wall compoundof the present disclosure include MONARCH 120 carbon black availablefrom Cabot Corporation of Boston, Mass. and TI-PURE R700 titaniumdioxide available from DuPont Chemicals of Wilmington, Del. In someembodiments, where provided, the amount of colorant is greater than 8%by weight. In some embodiments, the amount of colorant is less thanabout 20 percent by weight. In some embodiments, the amount of colorantis less than about 10 percent by weight. In some embodiments, the amountof colorant is less than 1 percent by weight, all percentages being ofthe total wall compound as formulated.

Yield Stress & Pseudoplastic Behavior

Regardless of whether one or more of the optional components mentionedabove are included, the wall compounds of the present disclosure areformulated to exhibit yield stress behavior. As used herein, the terms“yield stress fluid” and “yield stress behavior” refers to a material orcomposition that possesses the properties of a solid in the absence ofshear stress and the properties of a fluid (e.g., liquid) undersufficient shear stress. In some embodiments, the wall compounds of thepresent disclosure exhibit pseudoplastic-type behavior in addition to orin lieu of yield stress behavior. As used herein, the term“pseudoplastic” refers to a material or composition that exhibits shearthinning without significant initial resistance to deformation. The wallcompounds behave as non-Newtonian fluids under most use conditions, butmay also show linear (Newtonian) behavior at the highest levels ofstress and shear rate.

The yield stress behavior promotes easy spreading of the wall compoundon to a surface (such as a surface adjacent a wallboard joint), but oncethe user has stopped spreading, the wall compound quickly stops flowing.In some embodiments, the yield stress behavior is achieved by using apolyurethane-containing thickener package (e.g., HEUR based) incombination with hydrophobic dry fibrillated polyethylene fibers (orsimilar fiber material), hydrophilic rayon fibers (or similar fibermaterial), and suitable substantially spherical synthetic inorganicfillers (e.g., glass bubbles).

In some embodiments, the wall repair compounds of the present disclosurecan have a yield stress value or yield value (the force that must beapplied to a fluid layer before any movement is produced), meaning ithas an initial resistance to flow under stress but then is shearthinning, and when used, exhibits “cling,” meaning it has the ability atrest, to return to a pseudo-plastic or thixotropic gel. However, atstresses below the yield value, the viscosity increases substantiallyand resists flow, which is useful for preventing sagging or runningafter application. In presently preferred implementations, the yieldvalue is sufficiently high to prevent sagging or running before or afterspreading, and yet does not inhibit the mixing or application of thewall compound.

In some embodiments, the wall compound can have a yield stress value ofat least 200 Pa, in some embodiments, at least 350 Pa, in someembodiments at least 500 Pa, in some embodiments at least 600 Pa, insome embodiments at least 750 Pa, in some embodiments at least 1000 Pa.

In some embodiments, the wall compound can have a yield stress value ofno greater than 2000 Pa, no greater than 1750, no greater than 1500 Pa,and in some embodiments no greater than 1250 Pa. For wall compoundsparticularly useful as joint compounds, the yield stress value istypically less than 1000 Pa. This can help ensure the compound exhibitsthe desired fluid behavior upon shear stress levels that may be easierfor a user to generated by hand or tool.

In some embodiments, the wall compounds exhibit a viscosity at a stressof 500 Pa of a least 3000 Pa·s, in some embodiments at least 10,000Pa·s, in some embodiments at least 25,000 Pa·s and in some embodimentsat least 50,000 Pa·s (as measured accordingly to the Rheology TestMethod as described below). In some embodiments, the wall compoundsexhibit a Viscosity at 1500 Pa of stress of no greater than 10 Pa·s, insome embodiments no greater than 9 Pa·s, in some embodiments no greaterthan 8 Pa·s, in some embodiments no greater than 7 Pa·s, in someembodiments no greater than 5 Pa·s, in some embodiments no greater than4 Pa·s, in some embodiments no greater than 3 Pa·s, and in someembodiments no greater than 2 Pa·s.

In presently preferred implementations particularly suitable for use injoint filling, the wall compounds of the present disclosure have arelatively low yield stress value combined with a relatively highviscosity at low to no shear and a rapid transition to low viscosityupon application of sufficient force. It is desirable to have a highinitial viscosity in order that the compound can be as strong and thickas possible as applied to seams and yet have the lowest possibleviscosity so as to allow the compound to be easily spread acrosswallboards and joints.

The wall compounds are suitable for filling a joint seam, with orwithout reinforcement tape. In particularly advantageous embodiments,the wall compounds can fill a seam and provide a monolithic surfacewithout the need for joint reinforcement tape. The wall compounds of thepresent disclosure can be employed to repair a plethora of wall surfaceimperfections or defects (e.g., holes, cracks, etc.). Further, the wallcompounds of the present disclosure are well-suited to be applied into alarger hole (e.g., hole with a major dimension of at least 2 inches) ina vertical wall surface (e.g., following placement of a backing materialor panel onto a backside of the wall in a region of the hole).

In some embodiments, the wall compound of the present disclosure can beprovided to an end user as part of a kit. Exemplary kits can furtherinclude one or more tools, optionally a backing device for establishinga scaffolding structure “behind” the hole for receiving the wallcompound (e.g., non-limiting examples, of which are described in U.S.Pat. No. 9,828,782, entitled “Wall Hole Repair Device, Kit, and Method”,etc.

Methods of Use

The wall compounds of the present disclosure can be formulated andapplied in a manner akin to conventional spackling compounds, includingthe user spreading a quantity of the wall compound into the hole andalong an interior or exterior wall surface surrounding the hole with aspreading tool. In some embodiments, the wall compounds may be used witha conventional caulking tool. In other embodiments, the wall compoundsof the present disclosure can be provided to a user with a reduced watercontent (akin to a dough material). The corresponding methods of use ofthe present disclosure include the user rolling a volume of thedough-like wall compound to shape with the user's hand(s), and theninserting and pressing the shaped compound into the hole or otherdefect.

The wall compounds of the present disclosure are also well suited foradhering construction panels and fortifying joints. The wall compoundscan be used without joint reinforcement tape, which saves time and makeswall installation more accurate and reliable. The present wall compoundsare thus suitable in installation of various construction panels. Thesepanels include, but are not limited to, gypsum wallboards, paperlessgypsum panels and gypsum and/or cement-based tiles. In some embodiments,joint seams are filled with one or more layers of wall compound and thecomposition is allowed to self-level and create a polymerized matrixover the joint and some panel surface area. The seam can be then sandedif needed and is ready for decorative painting or another wall covering.

In some embodiments, one or more finishing compounds are applied tosurface of a wall compound matrix. The finishing compound can provide asmoother outer surface than certain implementations of wall compound,potentially reducing the amount of time spent sanding or otherwiseimproving the appearance of the joint seam. Finishing compounds of thepresent disclosure generally include a latex resin, a thickener package,and a synthetic filler material. Other optional ingredients (such assmoothing agents, colorants, primers and others listed above) may beincluded in various other embodiments. Finishing compounds typicallylack fibers of the type described herein, as fibers can potentiallycontribute to a rougher or uneven surface upon drying. Suitablefinishing compounds are described, for example, in U.S. Pat. No.8,507,857, entitled “Lightweight Wall Repair Compounds”.

For example, a finishing compound may include about 45 wt. % resin,about 25% synthetic filler, about 0.2 wt. % thickener, water, and otheradditives, each by weight of the total finishing compound as formulated.

In particular, advantageous circumstances, the use of a wall compoundand a finishing compound can reduce the time necessary to fill jointseams by up to 50%, as the typical filling process of the prior artrequires at least 3 coats or application steps for satisfactorycompletion (see FIG. 1).

In some other embodiments, the wall compound can be pre-made and storedon a shelf until needed. In other alternatives, the wall compounds canbe prepared from a kit at a construction site by mixing components suchas fibers, a resin, a thickener package, and synthetic filler, and othercomponents together with water.

Embodiments

1. A wall compound comprising: a latex resin or resin binder; athickener package; hydrophobic dry fibrillated fibers and hydrophilicfibers; and a filler material, wherein the filler consists ofsubstantially spherical synthetic inorganic filler, wherein the wallcompound exhibits yield stress behavior.2. The wall compound of embodiment 1, wherein the latex resin or resinbinder is one of a vinyl acrylic polymer or copolymer, an acrylicpolymer or copolymer, an acrylate polymer or copolymer, a polyvinylacetate polymer or copolymer, an ethylene vinyl acetate polymer orcopolymer, a styrene-butadiene polymer or copolymer, a polyacrylamidepolymer or copolymer, a natural rubber latex, a natural starch, asynthetic starch, and/or casein.3. The wall compound of any of the preceding embodiments, wherein thelatex resin or resin binder is 100% acrylate.4. The wall compound of any of the preceding embodiments, wherein thelatex resin or resin binder includes a resin blend.5. The wall compound of embodiment 4, wherein the resin blend includesone latex resin and one non-latex resin.6. The wall compound of any of the preceding embodiments, wherein thelatex resin or resin binder has a Tg of at least 15.7. The wall compound of any of the preceding embodiments, wherein thecompound has a yield stress value of at least 200 and no greater than1000 Pa.8. The wall compound of any of the preceding embodiments, wherein thethickener includes an alkali swellable emulsion.9. The wall compound of embodiment 8, wherein the thickener packagefurther includes a hydrophilic alkali swellable emulsion.10. The wall compound of claim 8 or 9, wherein the thickener packagingfurther includes a polyurethane based thickener.11. The wall compound of any of the preceding embodiments, wherein thethickener is present in an amount of about 1% by weight or less.12. The wall compound of any of the previous embodiments, wherein thefirst fiber type has a nominal length and the second fiber type has anominal length and the nominal length of the first fiber type is lessthan the nominal length of the second fiber type.13. The wall compound of embodiment 13, wherein the nominal length ofthe first fiber type is at least 10 times less than the nominal lengthof the second fiber type.14. The wall compound of embodiment 12, wherein the fibers includehydrophobic dry fibrillated polyethylene fibers and hydrophilic rayonfibers.15. The wall compound of embodiment 14, comprising a bimodal particlesize mixture of larger synthetic inorganic filler particles and smallersynthetic inorganic filler particles.16. The wall compound of embodiment 15, having a particle size ratio oflarger size synthetic inorganic filler particles to smaller sizesynthetic inorganic filler particles of at least about 5:1.17. The wall compound of any of embodiments 15-16, wherein the filler isat least one of glass bubbles and ceramic microspheres.18. The wall compound of any of the preceding embodiments, furthercomprising an adhesion promoter, an activator, a pH control agent, acolorant, a primer, a smoothing agent, water, and/or a preservative.19. The wall compound of any of the preceding embodiments, furthercomprising titanium dioxide present in an amount of between about 5% byweight and about 20% by weight.20. A wall compound comprising: a latex resin or resin binder; athickener package comprising an alkali swellable emulsion; two moretypes of fibers; and glass bubbles.21. The wall compound of embodiment 20, wherein the first fiber type hasa nominal length and the second fiber type has a nominal length and thenominal length of the first fiber type is less than the nominal lengthof the second fiber type.22. The wall compound of embodiment 20 or 21, wherein the nominal lengthof the first fiber type is at least 10 times less than the nominallength of the second fiber type.23. The wall compound of any of embodiments 20-22, wherein the fibersinclude hydrophobic dry fibrillated fibers and hydrophilic fibers.24. The wall compound of any of embodiments 23, wherein the fibersinclude hydrophobic dry fibrillated polyethylene fibers and hydrophilicrayon fibers.25. The wall compound of any of embodiments 20-24, wherein the latexresin or resin binder is one of a vinyl acrylic polymer or copolymer, anacrylic polymer or copolymer, an acrylate polymer or copolymer, apolyvinyl acetate polymer or copolymer, an ethylene vinyl acetatepolymer or copolymer, a styrene-butadiene polymer or copolymer, apolyacrylamide polymer or copolymer, a natural rubber latex, a naturalstarch, a synthetic starch, and/or casein.26. The wall compound of any of embodiments 20-25, wherein the latexresin or resin binder is 100% acrylate.27. The wall compound of any of embodiments 20-26, wherein the thickenerincludes an HEUR.28. The wall compound of any of embodiments 20-27, wherein the thickenerincludes a hydrophilic alkali swellable emulsion.29. The wall compound of any one of embodiments 20-28, comprising abimodal particle size mixture of larger synthetic inorganic fillerparticles and smaller synthetic inorganic filler particles.30. The wall compound of embodiment 29, having a particle size ratio oflarger size synthetic inorganic filler particles to smaller sizesynthetic inorganic filler particles of at least about 5:1.31. The wall compound of any of embodiments 20-30, further comprising anadhesion promoter, an activator, a pH control agent, a colorant, aprimer, a smoothing agent, water, and/or a preservative.32. The wall compound of any of embodiments 20-31, further comprisingtitanium dioxide, present in an amount of between about 5% by weight andabout 20% by weight.33. The wall compound of any of embodiments 24-32, wherein the wallcompound is a yield stress fluid and has a density of not greater than 6lbs/gal.34. A kit, comprising: the wall compound of any of embodiments 1-33; atool for applying, smoothing, or removing the wall compound.35. The kit of embodiment 34, further including instructions for usingat least one of the kit the wall compound and the tool.36. A method for affixing and holding two panels together at a jointseam, the method comprising: creating a joint seam by positioning twopanels such that the panels abut; and applying the wall compound ofembodiment 1-33 to the joint seam and some panel surface area around theseam.37. The method of embodiment 36, wherein the wall compound is allowed todry and create a film, and wherein the method further comprises applyingat least one coat of a wall compound over at least a portion of thefilm.38. The method of embodiment 36, wherein the method is performed withoutjoint reinforcement tape.39. The method of embodiment 36, wherein at least one of the panelsincludes gypsum.40. The method of embodiment 39, wherein the method further comprisesapplying at least one coat of a finishing compound over at least aportion of the film, the finishing compound including a latex resin orresin binder, a thickener package, filler, and optionally otheradditives.

EXAMPLES

In order that aspects of the present disclosure can be more fullyunderstood, the following examples are set forth. It should beunderstood that these examples are for illustrative purposes only, andare not to be construed as limiting the present disclosure in any manner

Rheology Test Method

The shear viscosity and yield stress of the compounds was measured usinga DHR-2 stress controlled rotational rheometer using 25 mm parallelplates (available from TA Instruments, New Castle, Del.). Temperaturewas controlled to 25° C. using a water-cooled Peltier stage. The sampleswere loaded onto the stage and compressed to a thickness of 1.05 mm tofully fill the gap between the parallel plates. (Whenever possible,tested samples were taken from the bottom of the jar to avoid dried outmaterial on the top of the jar, and were sampled without mixing tominimize the addition of shear history prior to testing.) The sampleedges were trimmed and then the gap was set to 1 mm. The stress ramp wasthen conducted by shearing the sample over a range of ascending shearstresses, steadily increasing the stress from 0 Pa to 10,000 Pa linearlyover the course of 60 seconds. (In most cases, the experiment stoppedprior to reaching the 10,000 Pa stress point, due to the high stressesspinning some material out from between the plates.)

Yield stress was measured as the onset point where the viscosity droppedover one order of magnitude over a narrow range of shear rates. Onsetpoints were determined by performing linear fitting to the viscosityboth in the low-stress range (where viscosity was largely independent ofthe applied stress) and in the highest-slope region of the curve, andfinding the stress value at which the two linear fits intersect.

Materials

A glossary of materials used in the Examples is provided in Table 1.

TABLE 1 RM Chemical Name Vendor ENCOR 626 100% Acrylic Latex ArkemaEmulsion Systems, (50% by weight solids, in water) Cary, NC ENCOR 627100% Acrylic Latex Arkema Emulsion Systems, (43.5% by weight solids, inwater) Cary, NC POLYPHASE P20T Fungicide solution Troy Corporation,Florham Active ingredient: 3-Iodo-2-propynyl butyl Park, NJ carbamate(20%% by weight solids, in water) MERGAL 186 Liquid preservative TroyCorporation, Florham 4,4-Dimethyloxazolidine Park, NJ Propylene GlycolPropylene Glycol n-Butyl Ether Sigma-Aldrich Butyl Ether MONARCH 120Carbon Black Cabot Corporation, Boston, MA AMP-952-Amino-2-methyl-1-propanol solution Angus Chemical Company, (95% byweight solids, in water) Buffalo Grove, IL RHEOTECH 4800 Acryliccopolymer aqueous dispersion Coatex (Arkema Group) (30% by weight totalsolids) COAPUR XS 83 Polyurethane aqueous solution Coatex (Arkema Group)(30% by weight total solids) RHEOTECH M 02 Acrylic copolymer aqueousdispersion Coatex (Arkema Group) (30% by weight total solids) CARBOWAX8000 Polyethylene Glycol (PEG), ~8000 MW Dow Chemical Company, Midland,MI CARBOWAX 400 Polyethylene Glycol (PEG), ~400 MW Dow Chemical Company,Midland, MI Mineral Oil Mineral oil Sigma-Aldrich SHORT STUFF E380FFibrillated high density polyethylene fibers MiniFIBERS, Inc.,(~0.55-0.80 mm length, 15 microns Johnson City, TN diameter) Rayon Fiber4.5 denier per filament, regular tenacity MiniFIBERS, Inc., viscoserayon fibers Johnson City, TN (0.125″ or 0.25″ lengths) ChartwellB-515.71W Adhesion promoter, an amino functional ChartwellInternational, Inc., metal organic compound Dudley, MA (33% by weightsolids, in water) RHODOLINE FT 100 Freeze thaw stabilizer Solvay USA,Inc., Poly(oxy-1,2-ethanediyl), alpha. [tris(1- Princeton, NJphenylethyl) phenyl]-.omega.-hydroxy- RHODOLINE 622 Defoamer Solvay USAInc., Oil/hydrophobic silica blend, containing Princeton, NJ additionalinorganic hydrophobes K20 Glass Bubbles Glass Bubbles 3M Company, St.Paul, MN iM16K Glass Bubbles Glass Bubbles 3M Company, St. Paul, MNCeramic Microspheres Ceramic Microspheres 3M Company, St. Paul, MN W-210HUBERCARB Q200 Calcium Carbonate J. M. Huber Corporation, Edison, NJTRONOX CR-828 Titanium dioxide Tronox Limited, Stamford, CT Zinc OxideSigma-Aldrich THIXOL 53 L Liquid acrylic self-associative thickenerCoatex (Arkema Group), (30% by weight solids, in water) Chester, SC PolyGlycerol-3 Solvay USA, Inc., Princeton, NJ POLYSTEP A-16 Sodiumdodecylbenzene sulfonate Stepan Company, (anionic surfactant)Northfield, IL PLURONIC L-62 Difunctional block copolymer BASFCorporation, terminating in primary hydroxyl groups Florhan Park, NJ(nonionic surfactant) ECODIS P 30 Polyacrylic dispersant sodium saltCoatex (Arkema Group), (42% by weight solids, in water) Chester, SCCOADIS BR 85 Polyether carboxylate dispersant Coatex (Arkema Group),(35% by weight solids, in water) Chester, SC

Comparative Examples 1 and 2

Comparative Example 1 was commercially available 3M Wall Repair FiberReinforced Compound. Comparative Example 2 was commercially availableUSG SHEETROCK PLUS 3 Joint Compound.

Examples 3-9

A batch of compounds was prepared by the following general method. Thefollowing equipment was provided: stainless steel containers, ahigh-speed mixer including a Cowles blade (for high shear mixing), and aHobart mixer including a tool appropriate for low shear mixing.

The acrylic latex and the fibers were initially mixed for 15-20 minutesin the stainless-steel mixing container with the Cowles blade (highshear). The temperature of the mix was maintained at less than 110° F.All remaining components other than the glass bubbles were then addedsequentially to the mixing container (using the Cowles blade), but runat a reduced speed to provide good mixing. The pH of the premix wasadjusted to pH=9 with AMP-95 if needed.

After the above solution was mixed uniformly, it was transferred to abowl and glass bubbles were added. All components were then slowly mixedusing the Hobart mixer. The compositions of the resultant compounds aresummarized in Table 2. The material amounts provided are in weightpercent (of the material as supplied by the vendor).

TABLE 2 Wall Compound compositions Example Example Example ExampleExample Example Example Material 3 4 5 6 7 8 9 ENCOR 626 43.2 45.3 45.545.5 ENCOR 627 44.0 48.0 40.2 SHORT STUFF 0.25 0.25 0.25 0.10 0.40 0.250.25 E380F Rayon Fiber 0.45 0.45 0.45 0.20 0.45 0.15 (0.125 in length)Rayon Fiber 0.45 0.30 (0.25 in length) Chartwell B- 0.25 0.25 0.25 0.250.25 0.25 515.71W RHEOTECH 4800 0.20 0.15 0.15 0.13 COAPUR XS 83 0.300.25 0.05 0.25 0.10 0.10 0.10 RHEOTECH M 02 0.20 POLYPHASE 0.30 0.300.30 0.30 0.30 0.30 0.30 P20T MERGAL 186 0.15 0.15 0.15 0.15 0.15 0.150.15 Propylene Glycol 0.50 1.00 1.00 0.25 0.25 0.50 0.50 Butyl EtherAMP-95 0.10 0.10 0.10 0.10 0.10 0.10 RHODOLINE FT 0.80 0.80 0.80 0.800.80 0.80 0.80 100 RHODOLINE 622 0.06 0.04 0.04 0.04 0.04 0.04 0.04MONARCH 120 0.003 0.003 0.003 0.003 0.003 0.003 0.003 CARBOWAX 1.00 1.001.00 1.00 0.50 8000 Mineral Oil 0.50 TRONOX CR-828 9.50 8.50 HUBERCARB2.00 2.00 2.00 2.00 2.00 Q200 Ceramic 5.00 5.00 11.00 Microspheres W-210 iM16K Glass 4.00 4.50 8.00 5.50 Bubbles K20 Glass Bubbles 22.0020.00 20.00 19.00 20.0 20.00 21.00 Water 23.34 20.41 25.21 18.21 18.7120.41 22.23

The rheological behavior of Comparative Examples 1 and 2 and Examples3-9 were tested using the Rheology Test Method described above. Resultsare provided in Table 3 and are graphically represented in FIG. 2.

TABLE 3 Yield stress and low-stress viscosity comparison. ViscosityViscosity Viscosity (Pa · s) (Pa · s) (Pa · s) Yield stress at 500 Pa at1000 Pa at 1500 Pa Material (Pa) stress stress stress Comparative 141059300 22800 863 Example 1 Comparative Not observed 753 251 25.7 Example2 Example 3 895 3510 160. 2.05 Example 4 434 52600 53.8 1.74 Example 51130 63700 17200 4.67 Example 6 354 695 14.7 1.37 Example 7 773 11200805 8.59 Example 8 607 7330 7.74 1.15 Example 9 831 8090 421 3.86

Except for the Comparative Example 2 compound, all other Examplecompounds exhibit higher viscosity at low stress, which makes them lesslikely to run or creep. They also have a rapid drop in viscosity at ayield stress, marked by the “onset” points on the graph in FIG. 2. Atthe yield stress, they transition from no flow (very high viscosity) toeasy flow (low viscosity). The viscosity of the Comparative Example 2compound gradually drops with stress, and does not have a yield stressat all. This makes it easy to apply this compound to the wall (nominimum stress to overcome before it flows), but it is likely to be more“runny” once it is on the wall.

The wall compounds of the present disclosure provide a markedimprovement over previous spackle or joint compounds, particularly inthe context of joint filling. In some embodiments, the use of fibers(optionally hydrophobic and hydrophilic fibers of differentmorphologies) in combination with an appropriate thickener (e.g.,HEUR-type thickener and other thickener without cellulosic or clay)provides desirable pseudoplastic-type and/or yield stress behavior. Insome embodiments, the use of a bimodal distribution of hollow glassmicrospheres from two different strength/size curves desirably rendersthe wall compound lightweight.

Examples 10-14

A batch of finishing compounds was prepared by the general method ofExamples 3-9. The compositions of the resultant compounds are summarizedin Table 4. The material amounts provided are in weight percent (of thematerial as supplied by the vendor).

TABLE 4 Finishing Compound compositions Example Example Example ExampleExample Material 10 11 12 13 14 HUBERCARB 5.0 4.30 4.30 4.30 4.30 Q200Ceramic 5.0 5.0 5.0 5.0 5.0 Microspheres W-210 K20 Glass 20.0 20.0 20.020.0 20.0 Bubbles ENCOR 626 45.0 46.0 46.0 46.0 ENCOR 627 46.0 Chartwell0.25 0.25 0.25 0.25 0.25 B-515.71W RHEOTECH 0.050 0.20 4800 COAPUR 0.100.20 0.20 XS 83 RHEOTECH 0.20 M 02 POLYPHASE 0.20 0.20 0.20 0.20 0.20P20T MERGAL 186 0.10 0.10 0.10 0.10 0.10 Propylene 0.50 1.00 1.00 1.001.00 Glycol Butyl Ether AMP-95 0.10 0.10 0.10 0.10 0.10 RHODOLINE 0.800.80 0.80 0.80 0.80 FT 100 MONARCH 0.004 0.004 0.004 0.004 0.004 120CARBOWAX 0.10 0.10 0.10 0.10 8000 Water 22.90 21.95 21.95 21.95 21.95

Examples 15-19

A batch of compounds was prepared by the general method of Examples 3-9.The compositions of the resultant compounds are summarized in Table 5.The material amounts provided are in weight percent (of the material assupplied by the vendor).

TABLE 5 Finishing Compound compositions Example Example Example ExampleExample Material 15 16 17 18 19 POLYPHASE 0.19 0.19 0.19 0.18 0.15 P20TMERGAL 186 0.10 0.10 0.10 0.10 0.10 Propylene 0.25 0.50 0.50 0.50 0.40Glycol Butyl Ether PolyGlycerol- 1.00 1.50 1.50 1.40 1.00 3 COADIS 0.800.80 0.80 0.75 0.60 BR 85 AMP-95 0.10 0.10 0.10 0.10 0.10 RHODOLINE 0.800.80 0.80 0.75 0.60 FT-100 RHODOLINE 0.03 0.03 0.01 0.030 0.02 622Chartwell 0.25 0.25 0.25 0.25 0.25 B-515.71W POLYSTEP 1.00 0.50 A16MONARCH 0.004 0.004 0.004 0.004 0.003 120 ENCOR 626 45.0 40.0 40.0 37.030.0 HUBERCARB 9.00 6.0 30.00 14.5 46.0 Q200 Zinc Oxide 1.00 1.00 0.50TRONOX 5.00 5.00 5.00 4.50 4.00 CR-828 THIXOL 53 L 0.50 0.40 0.40 0.400.30 RHEOTECH 0.10 0.10 0.10 0.10 M 02 iM16K Glass 3.5 6.0 5.5 BubblesK20 Glass 18.5 18.0 10.0 16.5 10.0 Bubbles Water 13.98 18.23 10.25 16.446.38

Examples 20-32

A batch of compounds was prepared by the general method of Examples 3-9.The compositions of the resultant compounds are summarized in Tables 6and 7. The material amounts provided are in weight percent (of thematerial as supplied by the vendor).

TABLE 6 Wall Compound compositions Example Example Example ExampleExample Example Material 20 21 22 23 24 25 iM16K Glass Bubbles 4.5 4.53.5 4.5 4.5 4.5 K-20 Glass Bubbles 21.0 21.0 18.0 21.0 21.0 21.0 TRONOXCR-828 5.00 Polyphase P2OT 0.19 0.19 0.19 0.19 0.19 0.19 MERGAL 186 0.100.10 0.10 0.10 0.10 0.10 Propylene Glycol 0.25 0.25 0.25 0.25 0.25 0.25Butyl Ether CARBOWAX 400 3.00 1.00 PolyGlycerol-3 3.00 1.00 1.00POLYSTEP A-16 1.00 1.00 PLURONIC L-62 2.00 2.00 ECODIS P 30 0.50 0.500.50 0.50 COADIS BR 85 0.80 0.80 SHORT STUFF 0.35 0.35 0.35 0.35 0.350.35 E380F Rayon Fiber 0.40 0.40 0.40 0.40 0.40 0.40 AMP-95 0.10 0.100.10 0.10 0.10 0.10 RHODOLINE FT 100 0.80 0.80 0.80 0.80 0.80 0.80RHODOLINE 622 0.03 0.03 0.03 0.03 0.03 0.03 Chartwell B-515.71W 0.250.25 0.25 0.25 0.25 0.25 MONARCH 120 0.004 0.004 0.004 0.004 0.004 0.004HUBERCARB Q200 8.00 8.00 7.84 6.00 6.00 6.00 ENCOR 626 46.2 46.2 45.047.0 47.0 47.0 Ceramic Microsphere W-210 THIXOL 53 L 0.30 0.30 0.50 0.500.50 0.50 RHEOTECH M 02 0.20 0.20 Zinc Oxide 1.0 1.0 1.0 1.0 Water 11.8311.53 14.89 15.03 16.03 16.03

TABLE 7 Wall Compound compositions Example Example Example ExampleExample Example Example Material 26 27 28 29 30 31 32 iM16K GlassBubbles 4.5 4.5 4.5 4.5 3.5 4.5 4.3 K-20 Glass Bubbles 21.0 21.0 21.021.0 18.0 18.0 18.0 TRONOX CR-828 5.00 6.0 3.5 POLYPHASE 20T 0.19 0.190.19 0.19 0.19 0.25 0.25 MERGAL 186 0.10 0.10 0.10 0.10 0.10 0.10 0.10Propylene Glycol 0.25 0.25 0.25 0.25 0.25 0.50 0.50 Butyl Ether CARBOWAX400 PolyGlycerol-3 1.00 1.00 1.00 1.00 POLYSTEP A-16 1.00 1.00 PLURONICL-62 ECODIS P 30 COADIS BR 85 0.80 0.80 0.80 0.80 0.80 SHORT STUFF 0.350.35 0.35 0.35 0.35 0.40 0.40 E380F Rayon Fiber 0.40 0.40 0.40 0.40 0.400.30 0.30 AMP-95 0.10 0.10 0.10 0.10 0.10 0.05 0.05 RHODOLINE FT 1000.80 0.80 0.80 0.80 0.80 0.63 0.56 RHODOLINE 622 0.03 0.03 0.01 0.030.03 0.02 0.02 Chartwell B-515.71W 0.25 0.25 0.25 0.25 0.25 0.25 0.25MONARCH 120 0.004 0.004 0.004 0.004 0.004 0.08 0.08 HUBERCARB Q200 6.006.00 6.00 6.00 5.00 7.30 ENCOR 626 46.2 46.2 45.0 47.0 47.0 40.00 40.00Ceramic Microsphere 6.00 W-210 THIXOL 53 L 0.50 0.50 0.50 0.50 0.50 0.400.20 RHEOTECH M 02 0.20 0.20 0.20 0.50 Zinc Oxide 1.0 1.0 1.0 1.0 1.0Water 15.33 16.33 17.75 15.73 14.73 23.32 23.70

The rheological behavior of Examples 20, 21, 31, and 32 were testedusing the Rheology Test Method described above. Results are provided inTable 8.

TABLE 8 Yield stress and low-stress viscosity comparison. ViscosityViscosity Viscosity (Pa · s) (Pa · s) (Pa · s) Yield stress at 500 Pa at1000 Pa at 1500 Pa Material (Pa) stress stress stress Example 20 75325100 92.9 9.08 Example 21 2670 589000 538000 330000 Example 31 693 397061.5 5.81 Example 32 1330 22800 5170 108

The recitation of all numerical ranges by endpoint is meant to includeall numbers subsumed within the range (i.e., the range 1 to 10 includes,for example, 1, 1.5, 3.33, and 10).

The patents, patent documents, and patent applications cited herein areincorporated by reference in their entirety as if each were individuallyincorporated by reference. It will be apparent to those of ordinaryskill in the art that various changes and modifications may be madewithout deviating from the inventing concepts set from above. Thus, thescope of the present disclosure should not be limited to the structuresdescribed herein. Those having skill in the art will appreciate thatmany changes may be made to the details of the above-describedembodiments and implementations without departing from the underlyingprinciples thereof. Further, various modifications and alterations ofthe present invention will become apparent to those skilled in the artwithout departing from the spirit and scope of the invention. The scopeof the present application should, therefore, be determined only by thefollowing claims and equivalents thereof.

What is claimed is:
 1. A wall compound comprising: a latex resin orresin binder present in an amount of about 50% by weight or less, basedon the total weight of the compound; a thickener package including analkali swellable emulsion, wherein the thickener package is present inamount of 1% by weight or less, based on the total weight of thecompound; hydrophobic dry fibrillated fibers and hydrophilic fibers; anda filler material consisting of substantially spherical syntheticinorganic filler, wherein the wall compound exhibits yield stressbehavior, having a yield stress value of at least 200 and no greaterthan 1000 Pa, and wherein the compound exhibits a Viscosity at 1500 Paof stress of no greater than 10 Pa·s, each as measured according to thedescription.
 2. The wall compound of claim 1, wherein the latex resin orresin binder is at least one of a vinyl acrylic polymer or copolymer, anacrylic polymer or copolymer, an acrylate polymer or copolymer, apolyvinyl acetate polymer or copolymer, an ethylene vinyl acetatepolymer or copolymer, a styrene-butadiene polymer or copolymer, apolyacrylamide polymer or copolymer, a natural rubber latex, a naturalstarch, a synthetic starch, and casein.
 3. The wall compound of claim 1,wherein the latex resin or resin binder is 100% acrylate.
 4. The wallcompound of claim 1, wherein the compound exhibits a Viscosity at 1500Pa of stress of no greater than 9 Pa·s.
 5. The wall compound of claim 1,wherein the thickener package includes a polyurethane based rheologymodifier.
 6. The wall compound of claim 1, wherein the fibers arepresent in total in an amount of no greater than 3% by weight, based onthe total weight of the compound.
 7. The wall compound of claim 1,wherein the hydrophobic dry fibrillated fibers have a length and thehydrophilic fibers have a length and the length of the hydrophobic dryfibrillated fibers is less than the length of the hydrophilic fibers. 8.The wall compound of claim 7, wherein the fibers include hydrophobic dryfibrillated polyethylene fibers and hydrophilic rayon fibers.
 9. Thewall compound of claim 1 wherein the filler is at least one of glassbubbles and ceramic microspheres.
 10. The wall compound of claim 1,further comprising at least one of an adhesion promoter, a humectant, asurfactant, a dispersing agent, an activator, a pH control agent, acolorant, a primer, a smoothing agent, water, and a preservative. 11.The wall compound of claim 1, further comprising titanium dioxidepresent in an amount of between about 5% by weight and about 20% byweight.
 12. The wall compound of claim 1, wherein the thickener includesan HEC and the alkali swellable emulsion is an HASE.
 13. A wall compoundcomprising: a latex resin or resin binder; present in an amount of about50% by weight or less, based on the total weight of the compound; athickener package comprising a rheology modifier and an alkali swellableemulsion; two or more types of fibers; and glass bubbles, wherein thewall compound exhibits yield stress behavior, having a yield stressvalue of at least 200 and no greater than 1000 Pa, and wherein thecompound exhibits a Viscosity at 1500 Pa of stress of no greater than 10Pa·s, each as measured according to the description.
 14. The wallcompound of claim 13, wherein the fibers include hydrophobic dryfibrillated polyethylene fibers and hydrophilic rayon fibers.
 15. Thewall compound of claim 1, wherein the thickener includes an HEC and thealkali swellable emulsion is an HASE.
 16. The wall compound of claim 1,wherein the wall compound is a yield stress fluid and has a density ofnot greater than 6 lbs/gal.
 17. A method for affixing and holding twopanels together at a joint seam, the method comprising: creating a jointseam by positioning two panels such that the panels abut; and applyingthe wall compound of claim 1 to the joint seam and some panel surfacearea around the seam.
 18. The method of claim 17, wherein the wallcompound is allowed to dry and create a film, and wherein the methodfurther comprises applying at least one coat of a wall compound over atleast a portion of the film.
 19. The method of claim 17, wherein themethod is performed without joint reinforcement tape.